Try this one .... on windows ...
curl.exe -XPATCH --data-binary "{\"ExtraPaths\":\"E:\\DVR;F:\\DVR\"}" http://192.168.1.196:8089/dvr
The Above Worked for me ....
{"activity":{},"busy":false,"clients":0,"disk":{"free":344920637440,"total":500105736192,"used":155185098752},"enabled":true,"extra_paths":["E:\\DVR","F:\\DVR"],"guide":{"num_lineups":1,"num_shows":1581,"num_airings":17517,"disk_size":84560354,"updated_at":1592053200},"keep":{"num":"","only":""},"last_backup":"2020-06-13T06:24:36.3603193-07:00","padding":{"end":"","start":""},"path":"S:\\DVR","stats":{"groups":0,"files":0,"jobs":0,"rules":0},"status":"running","transcoder_cache":{"size":0},"trash":{"after":"1"}}
This also works ...
curl.exe -XPATCH --data-binary "{\"ExtraPaths\":\"E:/DVR;F:/DVR\"}" http://192.168.1.196:8089/dvr