Smart Rules with collections

Is it possible to add a feature that would allow to add or exclude Movie Collections using smart rules?

I have a large movie collection and have created a shuffle station with a smart rule that shuffles the entire library. However there are some movies that I would like to exclude that are already in a movie collection.

Example: Star Wars, Harry Potter.

Could it be possible to add a feature that would allow a smart rule to shuffle all except specific collections?