Synology: 2 DVR instances with 2 IP addresses?

I've been running 2 DVR instances on Freenas for a while now with separate vnet ip addresses. I may be moving the DVR's to another location now that we have fiber access in my home town and I don't want to move the whole server so I'm considering a small Synology NAS just for DVR.

Having no experience with Synology apps, can I run two instances of the DVR and assign them different IP addresses similar to my current jail configuration on Freenas?